I can’t believe my eyes. That really is the Commander-in-Chief. I hope someone recognizes this photo so I can credit the cosplayer properly! Thanks to Kyle for sending this in!
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It is only in the anime that 
The Quinto Espada and representation of death’s aspect “despair”, Nnoitora Gilga was once the Octavo Espada when 
Captain of the 2nd Division and current Commander in Chief of the Secret Mobile Corps known as Onmitsukido, Soi Fon is a hard worker who believes strongly in following orders. She applies similar battle techniques to her master, Shihoin Yoruichi, engaging her opponents by using hand-to-hand combat with Shunko abilities. After asking Yoruichi why she did not take her when she left Soul Society, Yoruichi’s answer was not heard, but the two made amends.
The Captain of the 12th Division and President of the Shinigami Reseach Institute, Kurotsuchi Mayuri personifies the archetype of the mad scientist, viewing everyone as objects to be dissected in the lab. He takes great pride in his creations, such as his “daughter” Nemu, and condemns the concept of perfection. Mayuri has little regard for life or allegiances, going so far as turning his own subordinates as human bombs.